Eich, A., Wolf, B. A., Bennett, L. and Hess, S.

"Electro- and magneto-rheology of nematic liquid crystals: Experiment and non-equilibrium molecular dynamics (NEMD) computer simulation"

Journal-of-Chemical-Physics 2000, 113, 3829-3838.

Abstract: The viscosity of the nematic liquid crystal PCH-5 [4-(trans-4'-pentylcyclohexyl)-benzonitrile], measured in the presence of an electric field parallel to the gradient of the velocity, shows a complex dependence both on magnitude E of the electric field and on the shear rate . When plotted versus E2/ , all data points fall unto a master curve. In nonequilibrium molecular dynamics computer simulations, performed for a Gay-Berne model fluid, the corresponding influence of magnetic field on the viscosity was calculated. In both cases, the shape of the master curve for the viscosity can be computed by considering the competition between the torques exerted by the velocity gradient and by the orienting field. It involves the Leslie viscosity coefficients g1 and g2, the Miesowicz and Helfrich viscosities h1, h2 and h12. Thus it should be possible to extract these coefficients from the data. This is straightforward in the magnetic case since the molecules in the fluid "see" the externally applied field. The internal electric field, however, differs from the applied field E. When this effect is taken into account, using the known experimental values for dielectric coefficients e|| and e^, the electro-rheological master curve agrees very well with the experimental data. Values for the viscosity coefficients

preprint number: 211